K. A. Udachin, Yu. A. Dyadin, J. Lipkowski, “The Hexagonal Structure II of Clathrate Hydrate Me4NF·0.5Pr4NF·15H2O”, Mendeleev Commun., 1995, Volume 5, Issue 3,Pages 97

This article is cited in 3 papers

The Hexagonal Structure II of Clathrate Hydrate Me₄NF·0.5Pr₄NF·15H₂O

K. A. Udachin^a, Yu. A. Dyadin^a, J. Lipkowski^b

^a A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^b Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw, Poland

Abstract: The phase diagram of the tetramethylammonium fluoride−tetrapropylammonium fluoride−water system has been studied in the crystallization field; hydrate Me₄NF·0.5Pr₄NF·15H₂O (m.p. 21.7 °C) with hexagonal II unit cell: a = 12.290 Å, c = 59.354 Å has been discovered and so, as predicted by Jeffrey, the hexagonal structure II framework has been confirmed experimentally.

Language: English

DOI: 10.1070/MC1995v005n03ABEH000474