M. Xie, J. Gong, J. Zhou, J. Wang, Yu. Cao, T. Zhou, Ya. Dai, “Green coupling of 3,5-diamino-1<i>H</i>-1,2,4-triazole into the azo compound”, Mendeleev Commun., 2023, Volume 33, Issue 5,Pages <nobr>717

This article is cited in 2 papers

Communications

Green coupling of 3,5-diamino-1H-1,2,4-triazole into the azo compound

M. Xie^a, J. Gong^a, J. Zhou^a, J. Wang^a, Yu. Cao^a, T. Zhou^ab, Ya. Dai^ac

^a Department of Chemistry, Southwest University of Science and Technology, Mianyang, P.R. China
^b Xi'an Modern Chemistry Research Institute, Xi'an, P.R. China
^c School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang, P.R. China

Abstract: The nitrogen–nitrogen double bond between two molecules of 3,5-diamino-1H-1,2,4-triazole is successfully constructed using a one-step electrochemical coupling method. The oxidation occurs selectively when the electrochemical parameters are properly adjusted to provide a yield of 45.77%. Subsequently, the oxidative coupling of this substrate with electrochemically generated hydroxy nickel oxide or sodium hypochlorite is verified.

Keywords: electrochemical synthesis, conjugation reaction, active site, clean and efficient, triazoles, azo compounds, voltage control.

Language: English

DOI: 10.1016/j.mencom.2023.09.040

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