G. A. Dushenko, I. E. Mikhailov, A. Zschunke, N. Hakam, C. Muegge, V. I. Minkin, “Fluxional Behaviour of 7-Cyclohepta-1,3,5-trienyl Ethoxydithiocarbonate”, Mendeleev Commun., 1995, Volume 5, Issue 4,Pages <nobr>133

This article is cited in 11 papers

Fluxional Behaviour of 7-Cyclohepta-1,3,5-trienyl Ethoxydithiocarbonate

G. A. Dushenko^a, I. E. Mikhailov^a, A. Zschunke^b, N. Hakam^c, C. Muegge^c, V. I. Minkin^a

^a Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
^b Federal Institute for Materials Research and Testing, Berlin, Germany
^c Department of Chemistry, Humboldt University, Berlin, Germany

Abstract: Fast and reversible migrations of the ethoxydithiocarbonate group along the perimeter of the cycloheptatriene ring of 3 have been found to occur through a series of successive 1,7-sigmatropic shifts with an energy barrier in the range 17.4–17.9 kcal mol^–1.

Language: English

DOI: 10.1070/MC1995v005n04ABEH000491