V. V. Vashchenko, V. V. Kravets, L. A. Kutulya, “Bromination of 2-Arylideneketones”, Mendeleev Commun., 1995, Volume 5, Issue 4,Pages <nobr>159

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Bromination of 2-Arylideneketones

V. V. Vashchenko, V. V. Kravets, L. A. Kutulya

STC 'Institute for Single Crystals', National Academy of Sciences of Ukraine, Kharkov, Ukraine

Abstract: It is shown that the acid catalysed bromination of α,β-unsaturated ketones by NBS occurs in the α’-position in high yield; this reaction with chiral (1R,4R)-2-arylidene-p-menthanones is diastereoselective and results in 1R,4S-diastereoisomers.

Language: English

DOI: 10.1070/MC1995v005n04ABEH000506