E. P. Serebryakov, G. D. Gamalevich, A. V. Strakhov, A. A. Vasil'ev, “Enhancement and Reversal of Enantioselectivity of the Enzymatic Hydrolysis of (RS)-3-(4-Methoxycarbonyl)phenyl-2-methylprop-1-yl Acetate upon its Transformation into the η<sup>6</sup>-Arene(tricarbonyl)chromium Complex”, Mendeleev Commun., 1995, Volume 5, Issue 5,Pages <nobr>175

This article is cited in 5 papers

Enhancement and Reversal of Enantioselectivity of the Enzymatic Hydrolysis of (RS)-3-(4-Methoxycarbonyl)phenyl-2-methylprop-1-yl Acetate upon its Transformation into the η⁶-Arene(tricarbonyl)chromium Complex

E. P. Serebryakov^a, G. D. Gamalevich^a, A. V. Strakhov^b, A. A. Vasil'ev^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Abstract: Temporary introduction of the Cr(CO)₃ ‘ligand’ into the title substrate brings about a manifold increase in the enantioselectivity of its PPL-catalysed hydrolysis (characterised by the enantiomeric ratio parameter, E), and reverses the stereochemical result of the reaction.

Language: English

DOI: 10.1070/MC1995v005n05ABEH000509