U. Koelle, A. D. Ryabov, “The Effect of Chloride on the Electroreduction of NAD+ in the Presence of [Cp*RhIII]2+ Species”, Mendeleev Commun., 1995, Volume 5, Issue 5,Pages 187

This article is cited in 8 papers

The Effect of Chloride on the Electroreduction of NAD⁺ in the Presence of [Cp*Rh^III]²⁺ Species

U. Koelle^a, A. D. Ryabov^b

^a Institute of Inorganic Chemistry, Technical University of Aachen
^b G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation

Abstract: A cyclic voltammetry study of the η⁵-pentamethylcyclopentadienylrhodium (Cp*Rh) complexes [(Cp*Rh)₂(μ.-Cl)₃]⁺ and [Cp*Rh^III_aq]²⁺ at pH 6.05 in the absence and in the presence of nicotinamide cofactors indicates that the chloro complex is more advantageous for electrochemical reduction of NAD⁺ into NADH; the reverse oxidation of NADH by [(Cp*Rh)₂(μ-CI)₃]⁺ is insufficiently selective for practical applications according to the ¹H NMR data.

Language: English

DOI: 10.1070/MC1995v005n05ABEH000517