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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1995 Volume 5, Issue 6, Pages 218–219 (Mi mendc5107)

This article is cited in 5 papers

A Novel trans-1,2-Dimethyldiaziridine–Silver Nitrate Complex: Synthesis and Molecular and Crystal Structure

G. V. Shustova, A. B. Zolotoib, S. V. Konovalikhinb, L. O. Atovmyanb, R. G. Kostyanovskya

a N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
b Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation

Abstract: trans-1,2-Dimethyldiaziridine 1 reacts with AgNO3 yielding a stable complex 2(1:1 ratio); according to X-ray analysis silver ions are coordinated on the lone pairs of the diaziridine nitrogen atoms, and together with molecules of 1 of the opposite configuration form polymer chains.

Language: English

DOI: 10.1070/MC1995v005n06ABEH000533



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