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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1995 Volume 5, Issue 6, Pages 222–223 (Mi mendc5109)

This article is cited in 3 papers

Synthesis of π-Complexes of Codeine with Iron and Molybdenum

V. N. Kalinina, V. V. Derunova, L. Maatb, J. K. Parkc, H. Schmidhammerd

a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
b Laboratory of Organic Chemistry and Catalysis, Delft University of Technology, Delft, the Netherlands
c Dong Kook Pharmaceutical Co., Ltd., Seoul, Korea
d Institute of Pharmacy, University of Innsbruck, Innsbruck, Austria

Abstract: Treatment of 6β-chloro-6-deoxycodeine 1 or 8β-bromo-8-deoxypseudocodeine 2 with Fe(CO)5 or Fe2(CO)9 yields 6-demethoxythebaine 3 and the π-diene iron complex 4; compound 1 or 2 reacts with Mo(CO)6 to give the π-allylic molybdenum complexes 5 and 6, respectively.

Language: English

DOI: 10.1070/MC1995v005n06ABEH000535



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