L. G. Menchikov, A. V. Vorogushin, O. S. Korneva, O. M. Nefedov, “An Effective Method for Alcohol Preparation by Hydrolysis of Organohalides in the Presence of Copper and its Salts in Aqueous DMSO”, Mendeleev Commun., 1995, Volume 5, Issue 6,Pages <nobr>223

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An Effective Method for Alcohol Preparation by Hydrolysis of Organohalides in the Presence of Copper and its Salts in Aqueous DMSO

L. G. Menchikov^a, A. V. Vorogushin^b, O. S. Korneva^a, O. M. Nefedov^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Abstract: Hydrolysis of alkyl halides in the presence of copper and its salts in aqueous DMSO (molar ratio organohalide:CuSO₄·5H₂O:DMSO:H₂O = 1:1:10–20:12–25) at 100–117 °C gives alcohols in high yields. Aryl halides containing no activating substituents are inert under the reaction conditions.

Language: English

DOI: 10.1070/MC1995v005n06ABEH000536