W. E. Klotzbucher, M. A. Petrukhina, G. B. Sergeev, “Reactions of Samarium Atoms in Inert and Reactive Matrices”, Mendeleev Commun., 1994, Volume 4, Issue 1,Pages <nobr>5

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Reactions of Samarium Atoms in Inert and Reactive Matrices

W. E. Klotzbucher^a, M. A. Petrukhina^b, G. B. Sergeev^b

^a Max-Planck-Institute fur Strahlenchemie, Mulheim a.d. Ruhr, Germany
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: Cocondensation of samarium vapour with inert gases at cryogenic temperatures yields isolated samarium atoms and small clusters, while in complementary depositions with CO and N₂ novel carbonyl and dinitrogen complexes are formed. Surprisingly, ‘naked’ samarium atoms can be observed at 9 K in pure dinitrogen.

Language: English

DOI: 10.1070/MC1994v004n01ABEH000323