V. G. Slutsky, M. Hofmann, P. Schleyer, “On the Combustion of 1,6-Dicarba-<i>closo</i>-hexaborane”, Mendeleev Commun., 1994, Volume 4, Issue 1,Pages <nobr>12

This article is cited in 8 papers

On the Combustion of 1,6-Dicarba-closo-hexaborane

V. G. Slutsky^a, M. Hofmann^b, P. Schleyer^b

^a N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
^b Institut für Organische Chemie, Friedrich Alexander Universität Erlangen-Nürnberg, Erlangen, Germany

Abstract: The ab initio structures and thermodynamic properties of 1,6-dicarba-closo-hexaborane (1,6-C₂B₄H₆) and its isomers support the possibility that at very high combustion temperatures, rearrangement into a higher energy, but more reactive, isomer with an exo-[BH₂] group may precede the actual oxidation process.

Language: English

DOI: 10.1070/MC1994v004n01ABEH000327