E. S. Rudakov, A. I. Lutsyk, G. G. Gundilovich, “Propane Solubility in Aqueous Mineral Acids (0–100%): a Significant Difference in the Solvating Properties of H2SO4, HNO3 and H3PO4”, Mendeleev Commun., 1994, Volume 4, Issue 1,Pages 27

This article is cited in 2 papers

Propane Solubility in Aqueous Mineral Acids (0–100%): a Significant Difference in the Solvating Properties of H₂SO₄, HNO₃ and H₃PO₄

E. S. Rudakov, A. I. Lutsyk, G. G. Gundilovich

L.M. Litvinenko Institute of Physical Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, Donetsk, Ukraine

Abstract: Unexpectedly high differences in propane solubility in the systems HNO₃–H₂O (salting-in), H₃PO₄–H₂O (salting-out) and H₂SO₄–H₂O (salting-out at low H₂SO₄ concentrations and salting-in at high concentrations) have been revealed, and the data quantitatively interpreted within the framework of the previously suggested equation relating the excess amounts of solubility with the molar volume of a system; the general nature of these equations for systems of this type has been demonstrated.

Language: English

DOI: 10.1070/MC1994v004n01ABEH000336