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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1994 Volume 4, Issue 2, Pages 41–43 (Mi mendc5143)

This article is cited in 8 papers

Raman Spectra of Poly[di-n-propylsilylene]s and σ-σ Conjugation

S. S. Bukalova, L. A. Leitesa, V. A. Morozova, R. Westb, R. Menescalb

a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
b Department of Chemistry, University of Wisconsin, Madison, USA

Abstract: σ-σ-Conjugation in polysilylenes manifests itself in the Raman spectra qualitatively in a similar way to π-π-conjugation in polyenes, leading to a significant enhancement of lines corresponding to the stretching vibrations of the bonds participating in conjugation.

Language: English

DOI: 10.1070/MC1994v004n02ABEH000339



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