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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1994 Volume 4, Issue 2, Pages 50–51 (Mi mendc5147)

This article is cited in 5 papers

Reaction of Dihydroazinylidene Cyanoacetic Esters with Nitric Acid: A New Method for the Synthesis of Dihydroazinylidene Nitroacetonitriles

I. V. Oleinik, O. A. Zagulyaeva

N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: An approach to the synthesis of previously unknown dihydroazinylidene nitroacetonitriles (derivatives of pyridine, pyrimidine, pyrazine and pyridazine) has been developed involving nitration of the corresponding dihydroazinylidene cyanoacetic esters at the side chain α-C-atom and dealkoxycarbonylation of the resulting products.

Language: English

DOI: 10.1070/MC1994v004n02ABEH000343



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