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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1994 Volume 4, Issue 2, Pages 55–57 (Mi mendc5150)

This article is cited in 3 papers

Synthesis of 5-Trimethylsilyl-1,4-enynes from Ethoxy(trimethylsilyl)acetylene and Mono- and Diboron Allylic Compounds

Yu. N. Bubnov, A. V. Geiderikh, S. B. Golovin, M. E. Gurskii, M. Yu. Etinger, L. I. Lavrinovich, P. Yu. Meleshkin, S. V. Ponomarev, V. I. Zheludeva

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Allylic boranes and diboranes add to ethoxy(trimethylsilyl)acetylene with full rearrangement of the allylic moiety to give a series of new trimethylsilyl-substituted cyclic and acyclic 1,4-enynes and polyenynes with a terminal double bond.

Language: English

DOI: 10.1070/MC1994v004n02ABEH000346



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