Yu. H. Budnikova, Yu. M. Kargin, A. I. Samosova, “Homogeneous Mediator Reduction of Arylalkylphosphates”, Mendeleev Commun., 1994, Volume 4, Issue 2,Pages <nobr>58

This article is cited in 2 papers

Homogeneous Mediator Reduction of Arylalkylphosphates

Yu. H. Budnikova^a, Yu. M. Kargin^b, A. I. Samosova^a

^a A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
^b Department of Chemistry, V.I. Ul'yanov-Lenin Kazan State University, Kazan, Russian Federation

Abstract: The enthalpy and entropy of activation in the homogeneous electrochemical reduction of phosphoric acid esters [(PhO)_3–n(BuO)_nPO, n = 0–2] are assumed to reflect transition state stabilization of the electron transfer step due to partial bonding between substrate and mediator.

Language: English

DOI: 10.1070/MC1994v004n02ABEH000348