N. G. Razumova, A. E. Shumeiko, A. A. Afon'kin, A. F. Popov, “A New Phenomenon in Phase-transfer Catalysis (PTC): Topoinduced Stereoselectivity in the Phase-transfer Phenolysis of Cyclophosphazenes”, Mendeleev Commun., 1994, Volume 4, Issue 2,Pages <nobr>64

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A New Phenomenon in Phase-transfer Catalysis (PTC): Topoinduced Stereoselectivity in the Phase-transfer Phenolysis of Cyclophosphazenes

N. G. Razumova, A. E. Shumeiko, A. A. Afon'kin, A. F. Popov

L.M. Litvinenko Institute of Physical Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, Donetsk, Ukraine

Abstract: An increase in the ratio of the cis- and trans-isomers of bis(aryloxy)cyclotriphosphazenes 3—the products of the phenolysis of monoaryloxyphosphazenes in a liquid–liquid two-phase system—has been observed on passing from the reaction in the bulk of the organic phase to the reaction on the interface.

Language: English

DOI: 10.1070/MC1994v004n02ABEH000351