I. V. Kozhevnikov, A. Sinnema, R. J. Jansen, H. van Bekkum, “17O NMR Determination of Proton Sites in Solid Heteropolyacid H3PW12O4o”, Mendeleev Commun., 1994, Volume 4, Issue 3,Pages 92

This article is cited in 11 papers

¹⁷O NMR Determination of Proton Sites in Solid Heteropolyacid H₃PW₁₂O_4o

I. V. Kozhevnikov^a, A. Sinnema^b, R. J. Jansen^b, H. van Bekkum^b

^a G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^b Laboratory of Organic Chemistry and Catalysis, Delft University of Technology, Delft, the Netherlands

Abstract: Comparison of chemical shift values for solid-state and solution ¹⁷O NMR shows that, in the solid dehydrated H₃PW₁₂O₄₀, the terminal W=O oxygen atoms are the predominant protonation sites.

Language: English

DOI: 10.1070/MC1994v004n03ABEH000363