I. E. Mikhailov, G. A. Dushenko, O. E. Kompan, Yu. T. Struchkov, A. Zschunke, C. Muegge, V. N. Drozd, V. I. Minkin, “Circumambulatory Rearrangements of Dithioacyloxy Groups around the Cyclopentadiene Ring”, Mendeleev Commun., 1994, Volume 4, Issue 4,Pages <nobr>120

This article is cited in 4 papers

Circumambulatory Rearrangements of Dithioacyloxy Groups around the Cyclopentadiene Ring

I. E. Mikhailov^a, G. A. Dushenko^a, O. E. Kompan^a, Yu. T. Struchkov^b, A. Zschunke^c, C. Muegge^d, V. N. Drozd^e, V. I. Minkin^a

^a Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^c Federal Institute for Materials Research and Testing, Berlin, Germany
^d Department of Chemistry, Humboldt University, Berlin, Germany
^e K.A. Timiryazev Agricultural Academy, Moscow, Russian Federation

Abstract: Circumambulatory rearrangements of dithioacyloxy groups around the cyclopentadiene ring have been found to occur by a 3,3-sigmatropic shift (hetero-Cope) mechanism with energy barriers in the range of 24–30 kcal mol^–1.

Language: English

DOI: 10.1070/MC1994v004n04ABEH000375