A. M. Churakov, O. Yu. Smirnov, Yu. A. Strelenko, S. L. Ioffe, V. A. Tartakovsky, Yu. T. Struchkov, F. M. Dolgushin, A. I. Yanovsky, “Synthesis, Structure and Transformations of the First 1,2,3,4-Tetrazine-1-<i>N</i>-oxide”, Mendeleev Commun., 1994, Volume 4, Issue 4,Pages <nobr>122

This article is cited in 16 papers

Synthesis, Structure and Transformations of the First 1,2,3,4-Tetrazine-1-N-oxide

A. M. Churakov^a, O. Yu. Smirnov^a, Yu. A. Strelenko^a, S. L. Ioffe^a, V. A. Tartakovsky^a, Yu. T. Struchkov^b, F. M. Dolgushin^b, A. I. Yanovsky^b

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The first representative of the 1,2,3,4-tetrazine-N-oxides, 5,7-dibromobenzo-1,2,3,4-tetrazine-1-N-oxide 4b, has been obtained by intramolecular reaction of o-(tert-butylazoxy)phenyldiazonium tetrafluoroborate 2b. Compound 4b has been characterized by NMR spectroscopy and an X-ray diffraction study and its transformation 4b→ 5b→ 6b investigated; o-azidonitrosobenzene 5b was isolated and characterized for the first time.

Language: English

DOI: 10.1070/MC1994v004n04ABEH000376