T. S. Novikova, T. M. Mel'nikova, O. V. Kharitonova, V. O. Kulagina, N. S. Aleksandrova, A. B. Sheremetev, T. S. Pivina, L. I. Khmel'nitskii, S. S. Novikov, “An Effective Method for the Oxidation of Aminofurazans to Nitrofurazans”, Mendeleev Commun., 1994, Volume 4, Issue 4,Pages <nobr>138

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An Effective Method for the Oxidation of Aminofurazans to Nitrofurazans

T. S. Novikova, T. M. Mel'nikova, O. V. Kharitonova, V. O. Kulagina, N. S. Aleksandrova, A. B. Sheremetev, T. S. Pivina, L. I. Khmel'nitskii, S. S. Novikov

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: An effective method for the synthesis of nitrofurazans (NF) from aminofurazans (AF) has been developed based on H₂O₂-containing oxidizing mixtures with reduced acidity; a correlation between the ionization potentials of AF and the oxidative capacity of the mixtures has been found, and a calculated analytical method to determine the choice of oxidizing mixtures has been derived.

Language: English

DOI: 10.1070/MC1994v004n04ABEH000386