A. V. Nemukhin, I. M. Kolesnikov, V. A. Vinokurov, “Quantum Chemistry of Chemisorption of Ethylene at the Active Site of Alumophenylsiloxane”, Mendeleev Commun., 1994, Volume 4, Issue 4,Pages <nobr>144

Quantum Chemistry of Chemisorption of Ethylene at the Active Site of Alumophenylsiloxane

A. V. Nemukhin^a, I. M. Kolesnikov^b, V. A. Vinokurov^b

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b National University of Oil and Gas ‘Gubkin University’, Moscow, Russian Federation

Abstract: Quantum chemical calculations provide support for reaction mechanisms suggesting chemisorption of the ethylene molecule on the AIO₄ site of alumophenylsiloxane accompanied by π-bond rupture and the creation of cation-radicals.

Language: English

DOI: 10.1070/MC1994v004n04ABEH000389