V. D. Romanenko, A. V. Ruban, A. B. Roshenko, M. I. Povolotskii, T. V. Sarina, D. Gudat, E. Niecke, I. S. Zaslonko, “Reactions of Iminophosphanes with Chlorotris(triphenylphosphine)rhodium(I): Generation and NMR Identification of the First Iminophosphanerhodium(I) and Iminophosphanerhodium(III) Complexes”, Mendeleev Commun., 1993, Volume 3, Issue 1,Pages <nobr>7

This article is cited in 2 papers

Reactions of Iminophosphanes with Chlorotris(triphenylphosphine)rhodium(I): Generation and NMR Identification of the First Iminophosphanerhodium(I) and Iminophosphanerhodium(III) Complexes

V. D. Romanenko^a, A. V. Ruban^a, A. B. Roshenko^a, M. I. Povolotskii^a, T. V. Sarina^a, D. Gudat^b, E. Niecke^b, I. S. Zaslonko^c

^a Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
^b Anorganisch-Chemisches Institut der Universitat, Bonn, Germany
^c N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Iminophosphanes [RO-P=NAr] (R = Me, 2-MeC₆H₄; Ar = 2,4,6-Bu^t₃C₆H₂) 1a,b react with RhCIL₃ (L = Ph₃P) via ligand exchange to give _KP-iminophosphane complexes of rhodium(i) [RhCI(MeOP=NAr)₂L] 2 and [PhCI(2-MeC₆H₄OP=NAr)L₂] 3. Under analogous conditions, P-halogenoiminophosphanes [X-P=NAr] (X = CI, Br, I) 3a–c undergo a facile oxidative addition of the P—X bond, forming five-coordinate iminophosphanerhodium(iii) complexes of composition [L₂CI(X)Rh(<σ-P=BAr)] 5.

Language: English

DOI: 10.1070/MC1993v003n01ABEH000194