A. N. Kasatkin, Yu. A. Prokopenko, A. M. Khabibov, G. A. Tolstikov, “Cross-coupling of Organomanganese Derivatives of 3-Sulfolenes with Allyl and Propargyl Bromides. A Simple Synthesis of Functionalised Dienes”, Mendeleev Commun., 1993, Volume 3, Issue 1,Pages <nobr>17

This article is cited in 6 papers

Cross-coupling of Organomanganese Derivatives of 3-Sulfolenes with Allyl and Propargyl Bromides. A Simple Synthesis of Functionalised Dienes

A. N. Kasatkin^a, Yu. A. Prokopenko^a, A. M. Khabibov^a, G. A. Tolstikov^b

^a Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
^b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: Reactions of organomanganese derivatives of 3-sulfolene and 2-methyl-3-sulfolene with allyl- and propargyl bromides result in high yields of related 2-substituted or 2,5-disubstituted 3-sulfolenes; thermolysis of the cross-coupled products gives 1,3,6-trienes or 1,3-dien-6-ynes.

Language: English

DOI: 10.1070/MC1993v003n01ABEH000201