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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1993 Volume 3, Issue 2, Pages 39–40 (Mi mendc5253)

This article is cited in 3 papers

Synthesis of Cationic Trigonal-bipyramidal Clusters [MRh4(η-C5H5)4(PPh3)(μ3-CO)2]+PF6 (M = Cu, Ag, Au)

A. R. Kudinova, D. V. Muratova, M. I. Rybinskayaa, U. Turpeinenb

a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
b Department of Chemistry, University of Helsinki, Helsinki, Finland

Abstract: Novel mixed trigonal-bipyramidal clusters [MRh4(η-C5H5)4(PPh3)(μ3-CO)2]+PF6(M=Cu, Ag, Au) have been prepared by the reaction of Rh4(η-C5H5)(μ,3-CO)2 with [M(PPh3)]+ fragments, generated in situ in CH2CI2 from M(PPh3)Hal.

Language: English

DOI: 10.1070/MC1993v003n02ABEH000210



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