A. R. Kudinov, D. V. Muratov, M. I. Rybinskaya, U. Turpeinen, “Synthesis of Cationic Trigonal-bipyramidal Clusters [MRh4(η-C5H5)4(PPh3)(μ3-CO)2]+PF6– (M = Cu, Ag, Au)”, Mendeleev Commun., 1993, Volume 3, Issue 2,Pages 39

This article is cited in 3 papers

Synthesis of Cationic Trigonal-bipyramidal Clusters [MRh₄(η-C₅H₅)₄(PPh₃)(μ₃-CO)₂]⁺PF₆^– (M = Cu, Ag, Au)

A. R. Kudinov^a, D. V. Muratov^a, M. I. Rybinskaya^a, U. Turpeinen^b

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, University of Helsinki, Helsinki, Finland

Abstract: Novel mixed trigonal-bipyramidal clusters [MRh₄(η-C₅H₅)₄(PPh₃)(μ₃-CO)₂]⁺PF₆^–(M=Cu, Ag, Au) have been prepared by the reaction of Rh₄(η-C₅H₅)(μ,₃-CO)₂ with [M(PPh₃)]⁺ fragments, generated in situ in CH₂CI₂ from M(PPh₃)Hal.

Language: English

DOI: 10.1070/MC1993v003n02ABEH000210