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JOURNALS
// Mendeleev Communications
// Archive
Mendeleev Commun.,
1993
Volume 3,
Issue 2,
Pages
39–40
(Mi mendc5253)
This article is cited in
3
papers
Synthesis of Cationic Trigonal-bipyramidal Clusters [MRh
4
(η-C
5
H
5
)
4
(PPh
3
)(μ
3
-CO)
2
]
+
PF
6
–
(M = Cu, Ag, Au)
A. R. Kudinov
a
,
D. V. Muratov
a
,
M. I. Rybinskaya
a
,
U. Turpeinen
b
a
A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
b
Department of Chemistry, University of Helsinki, Helsinki, Finland
Abstract:
Novel mixed trigonal-bipyramidal clusters [MRh
4
(η-C
5
H
5
)
4
(PPh
3
)(μ
3
-CO)
2
]
+
PF
6
–
(M=Cu, Ag, Au) have been prepared by the reaction of Rh
4
(η-C
5
H
5
)(μ,
3
-CO)
2
with [M(PPh
3
)]
+
fragments, generated
in situ
in CH
2
CI
2
from M(PPh
3
)Hal.
Language:
English
DOI:
10.1070/MC1993v003n02ABEH000210
Fulltext:
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Steklov Math. Inst. of RAS
, 2025