N. N. Buravtsev, L. S. German, A. S. Grigor'ev, Yu. A. Kolbanovskii, A. A. Ovsyannikov, A. Yu. Volkonsky, “Trifluoromethylfluorocarbene Formation and Reactions under C2F5SiF3 Pulsed Adiabatic Compression Pyrolysis”, Mendeleev Commun., 1993, Volume 3, Issue 4,Pages 133

This article is cited in 10 papers

Trifluoromethylfluorocarbene Formation and Reactions under C₂F₅SiF₃ Pulsed Adiabatic Compression Pyrolysis

N. N. Buravtsev^a, L. S. German^b, A. S. Grigor'ev^a, Yu. A. Kolbanovskii^a, A. A. Ovsyannikov^a, A. Yu. Volkonsky^b

^a A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The formation of :CFCF₃, SiF₄ and (cis+trans)-2-C₄F₈ is demonstrated under the strictly homogeneous pyrolysis of C₂F₅SiF₃, using kinetic spectroscopy (at 250 and 465 nm) and chromatographic analysis, respectively. Pyrolysis of 2-C₄F₈ under the same conditions leads to the formation of an intermediate (C₄)^* which reveals absorption at 250 nm.

Language: English

DOI: 10.1070/MC1993v003n04ABEH000254