K. N. Zelenin, V. V. Alekseev, P. B. Terentiev, O. B. Kuznetsova, V. V. Lashin, V. V. Ovcharenko, V. V. Torocheshnikov, L. A. Khorseyeva, A. A. Sorokin, “Ring–Ring Tautomerism of Aldohexose Thiocarbohydrazones”, Mendeleev Commun., 1993, Volume 3, Issue 4,Pages <nobr>168

This article is cited in 9 papers

Ring–Ring Tautomerism of Aldohexose Thiocarbohydrazones

K. N. Zelenin^a, V. V. Alekseev^a, P. B. Terentiev^b, O. B. Kuznetsova^a, V. V. Lashin^b, V. V. Ovcharenko^b, V. V. Torocheshnikov^b, L. A. Khorseyeva^a, A. A. Sorokin^c

^a S.M. Kirov Military Medical Academy, St. Petersburg, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^c All-Russia Scientific Centre of Biologically Active Compounds, Moscow region, Russian Federation

Abstract: Mannose, galactose and glucose thiosemicarbazones, and mannose thiocarbohydrazones exist in DMSO solutions as tautomeric mixtures of pyranose and linear hydrazone forms, but in solutions of galactose and glucose thiocarbohydrazones there are also hexahydro-1,2,4,5-tetrazine-3-thione tautomers.

Language: English

DOI: 10.1070/MC1993v003n04ABEH000273