Zh. A. Krasnaya, E. V. Grechkina, V. S. Bogdanov, “Synthesis of Novel Substituted Phenols by Condensation of α,β-Unsaturated β-Dimethylaminoaldehyde Aminals with Triketones”, Mendeleev Commun., 1993, Volume 3, Issue 5,Pages <nobr>195

This article is cited in 2 papers

Synthesis of Novel Substituted Phenols by Condensation of α,β-Unsaturated β-Dimethylaminoaldehyde Aminals with Triketones

Zh. A. Krasnaya, E. V. Grechkina, V. S. Bogdanov

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Condensation of α,β-unsaturated β-dimethylaminoaldehydes with heptane-2,4,6-trione unexpectedly affords a new type of substituted phenols (4a–c; 5a,c) due to intramolecular cyclization accompanied by 1,6-deamination.

Language: English

DOI: 10.1070/MC1993v003n05ABEH000285