V. N. Kalinin, M. A. Yakovleva, V. V. Derunov, “Synthesis of σ-Heterocyclic Iron Complexes Based on [3+3] Cycloaddition to 1,3-Dipolar Reagents”, Mendeleev Commun., 1993, Volume 3, Issue 5,Pages <nobr>202

This article is cited in 2 papers

Synthesis of σ-Heterocyclic Iron Complexes Based on [3+3] Cycloaddition to 1,3-Dipolar Reagents

V. N. Kalinin, M. A. Yakovleva, V. V. Derunov

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Treatment of iron complex (η⁵-C₅H₅)Fe(CO)₂CH₂C≡CPh 1 with nitrogen-containing 1,3-dipolar reagents (nitrile oxides and azomethine ylide) yields six-membered σ-heterocyclic iron complexes, due to cycloaddition and subsequent 1,2-migration of the (η⁵–C₅H₅)₂Fe (CO) group.

Language: English

DOI: 10.1070/MC1993v003n05ABEH000290