V. A. Petrov, T. E. Mlsna, D. D. DesMarteau, “A New Route for the Preparation of Alkylfluorovinylsilanes and Stannanes”, Mendeleev Commun., 1993, Volume 3, Issue 6,Page 240

This article is cited in 5 papers

A New Route for the Preparation of Alkylfluorovinylsilanes and Stannanes

V. A. Petrov, T. E. Mlsna, D. D. DesMarteau

Howard L. Hunter Chemistry Laboratory, Clemson University, Clemson, SC, USA

Abstract: Methylfluorovinylsilanes and stannanes Me_4–xM(CF=CF₂)_x(M = Sn, x= 1; Si, x= 1,2) can be prepared in good to excellent yields by the reaction of CF₂=CFBr with a mixture of the corresponding Me_4–xMCI_x and P(NR₂)₃ in polar solvent. Similarly, the novel silane CF₃ (SiMe₃)C=CF₂ was obtained from CF₃CBr=CF₂

Language: English

DOI: 10.1070/MC1993v003n06ABEH000309