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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2023 Volume 33, Issue 6, Pages 826–828 (Mi mendc538)

Communications

Spectroscopic study of aqueous solutions of fullerene C60 mono-derivatives

O. V. Yamskovaa, V. S. Romanovaa, D. V. Kurilovb, V. A. Volkovc, L. O. Kononovb

a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
c N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Current spectral study of aqueous solutions of N-substituted fullerene C60 mono-derivatives of amino acid potassium salts showed that their solutions obey the Bouguer–Lambert–Beer law. On the basis of circular dichroism data, the optical activity was discovered not only for adducts with chiral amino acids but also for those with achiral molecules.

Keywords: C60 fullerene, fullerene amino acid derivatives, Bouguer–Lambert–Beer law, ultraviolet–visible spectroscopy, chirality, circular dichroism.

Language: English

DOI: 10.1016/j.mencom.2023.10.029



© Steklov Math. Inst. of RAS, 2025