A. G. Dedov, A. A. Karavaev, A. S. Loktev, P. V. Zemlianskii, M. N. Vagapova, K. I. Maslakov, K. A. Cherednichenko, S. V. Egazaryants, A. V. Khoroshilov, P. I. Ivanov, “HMFI/SiC – A novel efficient catalyst for green hydrocarbon production <i>via</i> bioisobutanol conversion”, Mendeleev Commun., 2023, Volume 33, Issue 6,Pages <nobr>832

This article is cited in 1 paper

Communications

HMFI/SiC – A novel efficient catalyst for green hydrocarbon production via bioisobutanol conversion

A. G. Dedov^ab, A. A. Karavaev^ab, A. S. Loktev^ab, P. V. Zemlianskii^b, M. N. Vagapova^a, K. I. Maslakov^c, K. A. Cherednichenko^b, S. V. Egazaryants^c, A. V. Khoroshilov^d, P. I. Ivanov^d

^a A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
^b National University of Oil and Gas ‘Gubkin University’, Moscow, Russian Federation
^c Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^d D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Abstract: Conversion of isobutyl alcohol over the HMFI/SiC composite has been for the first time studied. Isobutanol (bioisobutanol) considered as a promising product of biomass processing was catalytically converted into aromatic hydrocarbons of the benzene–toluene–xylene fraction (BTX) and olefins C₂–C₄ (mainly propylene and butenes). Compared with the pure zeolite, the incorporation of HMFI into the SiC matrix enhanced the yields of C₂–C₄ olefins and BTX in the isobutanol conversion due to increased densities of Brønsted and Lewis acid centers

Keywords: isobutanol, HMFI/SiC composite, catalysis, arenes, C₂–C₄ olefins, propylene, ‘green’ hydrocarbons.

Language: English

DOI: 10.1016/j.mencom.2023.10.031

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