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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1992 Volume 2, Issue 2, Pages 64–65 (Mi mendc5407)

This article is cited in 3 papers

Deprotonation and Subsequent Functionalization of Methyl Groups in Cationic Ruthenium Triple-decker Complexes

A. R. Kudinov, A. A. Filchikov, M. I. Rybinskaya

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The cationic complex [(η-C5Me5)Ru(μ,η-C5Me5)Ru(η-C5Me5)]+ undergoes deprotonation of the terminal ring methyl groups on treatment with BunLi-Bu’OK at – 78°C in tetrahydrofuran; subsequent treatment with EX reagents gives rise to functionalized complexes [(η-C5Me5)Ru(μ,η-C5Me5)Ru(η-C5Me4CH2E)]+ (E = Me, Me3Si, EtS).

Language: English

DOI: 10.1070/MC1992v002n02ABEH000136



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