O. M. Nefedov, M. A. Korolev, L. Zanathy, B. Solouki, H. Bock, “The Selective Thermal Fragmentation of 2,2’-Dipropynyl Sulfide to Propynethial and Allene”, Mendeleev Commun., 1992, Volume 2, Issue 2,Pages <nobr>67

This article is cited in 9 papers

The Selective Thermal Fragmentation of 2,2’-Dipropynyl Sulfide to Propynethial and Allene

O. M. Nefedov^a, M. A. Korolev^a, L. Zanathy^b, B. Solouki^c, H. Bock^c

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Institute of General and Inorganic Chemistry, Eotvos University, Budapest, Hungary
^c Institute of Inorganic Chemistry, Johann Wolfgang Goethe-University, Frankfurt, Germany

Abstract: The thermolysis of 2,2’-dipropynyl sulfide in a flow system under almost unimolecular conditions, which above 830 K selectively yields propynethial and allene, is optimized by photoelectron spectroscopic real-time gas analysis and, according to semiempirical energy hypersurface calculations, possibly proceeds via an intramolecular hydrogen transfer.

Language: English

DOI: 10.1070/MC1992v002n02ABEH000138