V. G. Shubin, M. M. Shakirov, S. M. Nagy, S. A. Osadchii, “6-lsopropylidene-1,2,3,4,5-pentamethylbicyclo[3.1.0]hex-3-en-2-yl Cation”, Mendeleev Commun., 1992, Volume 2, Issue 3,Pages <nobr>110

This article is cited in 4 papers

6-lsopropylidene-1,2,3,4,5-pentamethylbicyclo[3.1.0]hex-3-en-2-yl Cation

V. G. Shubin, M. M. Shakirov, S. M. Nagy, S. A. Osadchii

N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: The 6-lsopropylidene-1,2,3,4,5-pentamethylbicyclo[3.1.0]hex-3-en-2-yl cation, formed as a result of the rearrangement of4-(4′-methylpent-2′-yn-4′-yl)-1,2,3,4-tetramethylcyclobutenyl cation, shows no tendency to undergo a walk rearrangement but is capable of easy ring-opening to form the corresponding benzyl ion, 2-(2,3,4,5,6-pentamethylphenyl)-2-propyl cation.

Language: English

DOI: 10.1070/MC1992v002n03ABEH000159