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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1992 Volume 2, Issue 4, Pages 130–131 (Mi mendc5439)

This article is cited in 1 paper

The Absolute Configuration of Pyrazidole

A. E. Aliev, A. A. Sinitsyna, A. I. Bokanov, P. Yu. Ivanov, V. I. Shvedov, R. G. Kostyanovsky

N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The absolute configuration of 8-methyl-3-(-S-α-phenylethyl)-2,3,3a-S,4,5,6-hexahydro-1H-pyrazino-[3,2,1-jk]carbazole has been established on the basis of the stereospecificity of its 1H and 13C NMR parameters, which, taking into account the synthetic scheme, provides evidence for an S-configuration of the aymmetric C-3a atom in the original ( + )-pyrazidole.

Language: English

DOI: 10.1070/MC1992v002n04ABEH000168



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