S. N. Konchenko, V. A. Maksakov, I. Yu. Filippov, A. V. Virovets, N. V. Podberezskaya, “Synthesis and Structure of Cluster Monomer Fe2(CO)6(μ-SCH2CH=CH2)(μ3-S)Fe(CO)2(η5-C5H5)”, Mendeleev Commun., 1992, Volume 2, Issue 4,Pages 165

This article is cited in 3 papers

Synthesis and Structure of Cluster Monomer Fe₂(CO)₆(μ-SCH₂CH=CH₂)(μ₃-S)Fe(CO)₂(η⁵-C₅H₅)

S. N. Konchenko, V. A. Maksakov, I. Yu. Filippov, A. V. Virovets, N. V. Podberezskaya

A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: The reaction of complex Fe₂(CO)₆S₂ 1 with allylmagnesium chloride in tetrahydrofuran yields the compound Fe₂(CO)₆(μ-SCH₂CH=CH₂)(μ-SMgCI) 2a, whose treatment with CpFe(CO)₂X (X = l, Cl; Cp = η⁵-C₅H₅) leads to the title compound 3, the structure of which has been determined by X-ray diffraction analysis.

Language: English

DOI: 10.1070/MC1992v002n04ABEH000189