V. I. Nefedov, I. B. Baranovskii, A. V. Chuvaev, G. N. Dolenko, T. M. Ivanova, “Effective Atomic Charge and Extraatomic Relaxation Energies in Coordinated Ligands”, Mendeleev Commun., 1991, Volume 1, Issue 1,Pages <nobr>3–4</nobr>

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Mendeleev Commun., 1991 Volume 1, Issue 1, Pages 3–4 (Mi mendc5463)

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Effective Atomic Charge and Extraatomic Relaxation Energies in Coordinated Ligands

V. I. Nefedov^a, I. B. Baranovskii^a, A. V. Chuvaev^a, G. N. Dolenko^b, T. M. Ivanova^c

^a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
^c Russian Research Centre 'Research Institute of Organic Intermediates and Dyes', Moscow, Russian Federation

Abstract: The effective atomic charge and extraatomic relaxation energies of donor atoms in ligands change as expected on coordination and depend on the strength of the metal—ligand bond which is governed mainly by the mutual influence of ligands in the coordination compounds investigated.

Language: English

DOI: 10.1070/MC1991v001n01ABEH000002

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