I. A. Krol, Z. A. Starikova, V. S. Sergienko, E. O. Tolkacheva, “Deprotonation of an <i>α</i>-Hydroxy Group in 1-Hydroxyethylidenediphosphonic Acid and an Unusual Type of Dimeric Anion in the Structure of Na<sub>5</sub>[Mo<sub>2</sub>O<sub>6</sub>(L*)]·14H<sub>2</sub>O”, Mendeleev Commun., 1991, Volume 1, Issue 1,Pages <nobr>7–8</nobr>

RUS ENG

JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1991 Volume 1, Issue 1, Pages 7–8 (Mi mendc5466)

This article is cited in 7 papers

Deprotonation of an α-Hydroxy Group in 1-Hydroxyethylidenediphosphonic Acid and an Unusual Type of Dimeric Anion in the Structure of Na₅[Mo₂O₆(L*)]·14H₂O

I. A. Krol^a, Z. A. Starikova^b, V. S. Sergienko^c, E. O. Tolkacheva^a

^a State Research Institute of Chemical Reagents and Highly Pure Chemical Substances, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^c N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The synthesis and X-ray analysis of a complex containing a deprotonated α-hydroxy group, Na₅[Mo₂O₆(L*)]•14H₂O, are presented; the dimeric anion has an unusual structure with a different number of terminal oxygen atoms in the ‘yl’ groups of the two moieties of the dimer (MoO₃ and MoO₂).

Language: English

DOI: 10.1070/MC1991v001n01ABEH000005

© Steklov Math. Inst. of RAS, 2025