Mendeleev Commun., 1991 Volume 1, Issue 1, Pages 22–24
(Mi mendc5475)
This article is cited in
6 papers
Ion-radical Gold–(I) Tetracyanoethylene Complex [(Ph3 P)2 Au]+ [(NC)2 C=C(CN)2 ]− · T. V. Baukova a ,
O. G. Ellert b ,
L. G. Kuz'mina b ,
N. V. Dvortsova b ,
D. A. Lemenovskii c ,
A. Z. Rubezhov a a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation c Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation Abstract:
The reaction of (NC)
2 C=C(CN)
2 (TCNE) with [O(AuPPh
3 )
3 ]
+ BF
4 − produces the novel ion–radical complex [(Ph
3 P)
2 Au]
+ [TCNE]
− •
1 ; the X-ray crystal structure, magnetic data and ESR spectra of
1 have been determined.
Language: English
DOI:
10.1070/MC1991v001n01ABEH000014
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