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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1991 Volume 1, Issue 4, Pages 118–119 (Mi mendc5533)

This article is cited in 12 papers

Selective Hydrogenolysis of the C–F Bond

M. E. Vol'pina, N. V. Shevchenkoa, G. I. Bolestovaa, I. G. Abramovb, Yu. A. Fialkova, Z. N. Parnesa

a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
b Department of Organic Chemistry, Yaroslavl State Technical University, Yaroslavl, Russian Federation

Abstract: It has been shown that the C–F bond may be selectively hydrogenolysed under the action of HSiEt3 in the presence of AICI3, when the α-position of the C–F bond is occupied by a phenyl group or by a heteroatom with an unshared electron pair

Language: English

DOI: 10.1070/MC1991v001n04ABEH000072



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