A. Torvisco, M. Wolf, M. Traxler, D. Gudat, F. Uhlig, “New insights into the selective and systematic preparation of arylgermanium hydrides”, Mendeleev Commun., 2022, Volume 32, Issue 1,Pages <nobr>22

This article is cited in 2 papers

Communications

New insights into the selective and systematic preparation of arylgermanium hydrides

A. Torvisco^a, M. Wolf^a, M. Traxler^a, D. Gudat^b, F. Uhlig^a

^a Institute für Anorganische Chemie, Technische Universität Graz, Graz, Austria
^b Institute of Inorganic Chemistry, University of Stuttgart, Stuttgart, Germany

Abstract: A series of novel arylgermanium hydrides Ar_nGeH₄_–n (n = 1–3) and diaryl(chloro)germanium hydrides Ar₂Ge(Cl)H were synthesized and characterized. Systematic preparation and purification were achieved via the lithium chloride–triflic acid and the optimized Grignard route. Arylgermanium hydrides ArnGeH_4–_n (Ar = 2,5-Me₂C₆H₃, n = 1–3) were characterized by ¹H and ⁷³Ge NMR spectroscopy and single crystal X-ray diffractometry.

Keywords: organogermanium compounds, arylgermanium hydrides, aryl(chloro)germanium hydrides, solid-state structures, ¹H NMR spectroscopy, ⁷³Ge NMR spectroscopy.

Language: English

DOI: 10.1016/j.mencom.2022.01.006

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