A. V. Kansuzyan, S. D. Farafonova, E. A. Saverina, I. V. Krylova, V. A. Balycheva, A. Ya. Akyeva, A. G. Medvedev, E. N. Nikolaevskaya, M. P. Egorov, P. V. Prikhodchenko, M. A. Syroeshkin, “Highly soluble germanium dioxide as a new source of germanium for derivatization with organic compounds”, Mendeleev Commun., 2022, Volume 32, Issue 1,Pages <nobr>25

This article is cited in 5 papers

Communications

Highly soluble germanium dioxide as a new source of germanium for derivatization with organic compounds

A. V. Kansuzyan^a, S. D. Farafonova^ab, E. A. Saverina^a, I. V. Krylova^a, V. A. Balycheva^ab, A. Ya. Akyeva^a, A. G. Medvedev^c, E. N. Nikolaevskaya^a, M. P. Egorov^a, P. V. Prikhodchenko^c, M. A. Syroeshkin^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
^c N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: In modern germanium chemistry, toxic, corrosive and water- sensitive halogen and alkoxy derivatives, or poorly reactive polymeric dioxide are generally utilized. Recently developed highly water-soluble germanium dioxide was herein treated with diols and N-donor bases to produce novel highly reactive hydrophilic germanium source suitable for further derivatization.

Keywords: germanium chemistry, synthesis, highly soluble GeO₂, germanium oxide, catechols, cyclic voltammetry, UV spectroscopy, thermal analysis.

Language: English

DOI: 10.1016/j.mencom.2022.01.007

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