B. Minkovich, A. Kaushansky, N. Fridman, D. Bravo-Zhivotovskii, Y. Apeloig, “η<sup>2</sup>-Phosphasilene transition metal complexes – a novel building block for hetero-multimetallic complexes”, Mendeleev Commun., 2022, Volume 32, Issue 1,Pages <nobr>28

This article is cited in 1 paper

Communications

η²-Phosphasilene transition metal complexes – a novel building block for hetero-multimetallic complexes

B. Minkovich, A. Kaushansky, N. Fridman, D. Bravo-Zhivotovskii, Y. Apeloig

Schulich Faculty of Chemistry, Technion-Israel Institute of Technology, Haifa, Israel

Abstract: Compound η²-((R₃Si)₂Si=PH)–Pt(dmpe) was synthesized by trapping the transient phosphasilene, (R₃Si)₂Si=PH. Novel hetero-bi- and tri-metallic complexes derived from η²-((R₃Si)₂Si=PH)–Pt(dmpe) containing Pt with Li, Zn, Hg and Ag metals were synthesized and characterized by multi- nuclear NMR spectroscopy and X-ray crystallography. The synthesis of η²-((R₃Si)₂Si=PH)–Pt(dmpe), and its bonding character are discussed; a 1,2-silyl shift from silicon to phosphorus (a ‘Brook-type’ rearrangement) within the coordination sphere of a Pt complex is also reported.

Keywords: silicon, phosphorus, phosphasilene, heavy main-group multiple bonds, hetero-bimetallic complex, π-complex, transition metal complex, NMR, X-ray structures.

Language: English

DOI: 10.1016/j.mencom.2022.01.008

	*Supplementary materials:*
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