Ya. Egawa, Ch. Kobuna, N. Takeda, M. Unno, “Synthesis of Janus cube containing Si–H moieties”, Mendeleev Commun., 2022, Volume 32, Issue 1,Pages <nobr>35

This article is cited in 1 paper

Communications

Synthesis of Janus cube containing Si–H moieties

Ya. Egawa^ab, Ch. Kobuna^b, N. Takeda^b, M. Unno^b

^a Department of Chemistry, Faculty of Science, Kanagawa University, Kanagawa, Japan
^b Department of Chemistry and Chemical Biology, Graduate School of Science and Technology, Gunma University, Gunma, Japan

Abstract: The first representative of the Janus cube with hydrogen substituents was obtained from all-cis-[BuⁱSiO(OH)]₄ by its capping with HSiCl₃ followed by gentle hydrolysis causing internal condensation. The compound has an extremely low maximum loss temperature, which is approximately halfway between H₈Si₈O₁₂ and (octaisobutyl)octasilsesquioxane.

Keywords: siloxanes, octasilsesquioxanes, organosilicon compounds, Janus particle, TG-DTA.

Language: English

DOI: 10.1016/j.mencom.2022.01.010

	*Supplementary materials:*
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