A. A. Nikolin, A. A. Korlyukov, E. P. Kramarova, A. R. Romanenko, D. E. Arkhipov, D. V. Tarasenko, S. Yu. Bylikin, Yu. I. Baukov, V. V. Negrebetsky, “Synthesis and structure of (O → Si)-chelate fluorosilane, a novel complex of pentacoordinate silicon with <i>N</i>-acetylvaline”, Mendeleev Commun., 2022, Volume 32, Issue 1,Pages <nobr>37

This article is cited in 6 papers

Communications

Synthesis and structure of (O → Si)-chelate fluorosilane, a novel complex of pentacoordinate silicon with N-acetylvaline

A. A. Nikolin^a, A. A. Korlyukov^ab, E. P. Kramarova^a, A. R. Romanenko^c, D. E. Arkhipov^b, D. V. Tarasenko^a, S. Yu. Bylikin^d, Yu. I. Baukov^a, V. V. Negrebetsky^a

^a N.I. Pirogov Russian National Research Medical University, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^c D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
^d The Open University, Walton Hall, Milton Keynes, UK

Abstract: A novel organosilicon complex of N-acetylvaline was synthesized by the reaction of the relative disiloxane derivative with BF3 etherate. According to X-ray and NMR data, the silicon atom of the final product is pentacoordinated in both the solid state and solution. The coordination state of silicon was correctly predicted by quantum-chemical calculations.

Language: English

DOI: 10.1016/j.mencom.2022.01.011

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