T. Iwamoto, A. Kobayashi, N. Akasaka, Sh. Ishida, “Skeletal isomerism within 1,3-disilabicyclo[1.1.0]butane and 2,3-disilabuta-1,3-diene derivatives”, Mendeleev Commun., 2022, Volume 32, Issue 1,Pages <nobr>39

This article is cited in 3 papers

Communications

Skeletal isomerism within 1,3-disilabicyclo[1.1.0]butane and 2,3-disilabuta-1,3-diene derivatives

T. Iwamoto, A. Kobayashi, N. Akasaka, Sh. Ishida

Department of Chemistry, Graduate School of Science, Tohoku University, Sendai, Japan

Abstract: A bis-adamantane-spiro-fused 1,3-bis(triisopropylsilyl)-1,3-disilabicyclo[1.1.0]butane equilibrates with the corresponding 2,3-bis(triisopropylsilyl)-1,3-disilabuta-1,3-diene with a ratio of 1:19. The 1,3-disilabuta-1,3-diene was fully characterized by a combination of multinuclear NMR and UV-VIS spectroscopies, elemental analysis, and single-crystal X-ray diffraction analysis.

Keywords: Skeletal isomerization, Bicyclo[1.1.0]butanes, 1,3-Disilabicyclo[1.1.0]butanes, 2,3-Disilabuta-1,3-dienes, Organosilicon compounds, Tetrasilanes.

Language: English

DOI: 10.1016/j.mencom.2022.01.012

	*Supplementary materials:*
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