H. H. Cramer, L. Bührmann, M. Schmidtmann, T. Müller, “A phenyl-substituted germole dianion and its reaction with hafnocene dichloride”, Mendeleev Commun., 2022, Volume 32, Issue 1,Pages <nobr>46

This article is cited in 3 papers

Communications

A phenyl-substituted germole dianion and its reaction with hafnocene dichloride

H. H. Cramer, L. Bührmann, M. Schmidtmann, T. Müller

Institute of Chemistry, Carl von Ossietzky University Oldenburg, Oldenburg, Germany

Abstract: The reaction of phenyl-substituted dipotassium germacyclo-pentadienediide with one equivalent of hafnocene dichloride at low temperature provides a bicyclic germylene. With two equivalents of hafnocene dichloride, a dinuclear hafnium complex with a mmm-coordinating germolyl dianion ligand is formed.

Keywords: Germanium, Germoles, Organogermanium compounds, Hafnium complexes, Anions, Aromaticity.

Language: English

DOI: 10.1016/j.mencom.2022.01.014

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