R. Fischer, Ch. Marschner, “Elimination of bis(trimethylsilyl)stannylene from tris(trimethylsilyl)stannylated zirconocene and hafnocene chlorides”, Mendeleev Commun., 2022, Volume 32, Issue 1,Pages <nobr>52

This article is cited in 2 papers

Communications

Elimination of bis(trimethylsilyl)stannylene from tris(trimethylsilyl)stannylated zirconocene and hafnocene chlorides

R. Fischer, Ch. Marschner

Institute für Anorganische Chemie, Technische Universität Graz, Graz, Austria

Abstract: Reactions of (Me₃Si)₃SnK with Cp₂MCl₂ (M = Zr, Hf) give the respective stannylated metallocene chlorides. These complexes display a tendency to eliminate bis(trimethylsilyl)-stannylene under Cp₂M(Cl)SiMe₃ formation.

Keywords: Stannylated compounds, Group 4 elements, Metallocenes, Stannylene, Tin, Silicon, Zirconium, Hafnium.

Language: English

DOI: 10.1016/j.mencom.2022.01.016

	*Supplementary materials:*
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