A. G. Medvedev, M. Yu. Sharipov, D. A. Grishanov, A. V. Eshtukov, A. V. Churakov, I. A. Buldashov, P. A. Egorov, O. Lev, P. V. Prikhodchenko, “Synthesis and crystal structure of triphenyltin and lead complexes with organic peroxides”, Mendeleev Commun., 2022, Volume 32, Issue 1,Pages <nobr>57

This article is cited in 7 papers

Communications

Synthesis and crystal structure of triphenyltin and lead complexes with organic peroxides

A. G. Medvedev^a, M. Yu. Sharipov^a, D. A. Grishanov^ab, A. V. Eshtukov^c, A. V. Churakov^a, I. A. Buldashov^a, P. A. Egorov^a, O. Lev^b, P. V. Prikhodchenko^a

^a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Casali Center of Applied Chemistry, The Hebrew University of Jerusalem, Jerusalem, Israel
^c State Scientific Research Institute of Chemistry and Technology of Organoelement Compounds, Moscow, Russian Federation

Abstract: Crystalline triphenyltin cumyl and tert-butyl peroxides (Ph₃SnOOCMe₂Ph and Ph₃SnOOBu^t, respectively) and triphenyllead cumyl peroxide (Ph₃PbOOCMe₂Ph) were synthesized and characterized by single crystal and powder X-ray diffraction, NMR, FTIR and Raman spectroscopies, TG and DSC analysis. The formation of triphenyltin tert-butyl peroxide in benzene in the presence of a base was proved by ¹¹⁹Sn, ¹³C and ¹H NMR spectroscopy. To the best of our knowledge, the obtained complexes are the first structurally characterized coordination compounds of tin and lead with organic peroxides.

Keywords: Peroxo complexes, Organic hydroperoxides, Coordination peroxo compounds, Lead, Tin, Hydrogen peroxide.

Language: English

DOI: 10.1016/j.mencom.2022.01.018

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